GKS100M | Aquamicron™ Titrant SS 10mg
GKS30M | Aquamicron™ Titrant SS 3mg
GKS10M (Manufactured before Feb, 2017) | Aquamicron™ Titrant SS 1mg
GKS10M (LOT No.B17232) | Aquamicron™ Titrant SS 1mg
GKS10M | Aquamicron™ Titrant SS 1mg
GMW20 | Aquamicron™ Standard Water-Methanol 2mg
GMW05 | Aquamicron™ Standard Water-Methanol 0.5mg
GML | Aquamicron™ Solvent ML
GCM | Aquamicron™ Solvent CM
GME | Aquamicron™ Solvent ME
GPE | Aquamicron™ Solvent PE
GPP | Aquamicron™ Solvent PP
GMS | Aquamicron™ Solvent MS
GFM(Manufactured before May,2013) | Aquamicron™ Solvent FM
GFM | Aquamicron™ Solvent FM
GCP | Aquamicron™ Solvent CP
SKT | Dehydrated Solvent KT
SSU(Manufactured before May,2013) | Aquamicron™ Solvent SU
SSU | Aquamicron™ Solvent SU
SAMA(Manufactured before May,2013) | Aquamicron™ AS
SAMA | Aquamicron™ AS
SAMAK | Aquamicron™ AKS
XAMA | Aquamicron™ AX
XAMA01 | Aquamicron™ AX01
XAMI | Aquamicron™ AXI
CXU | Aquamicron™ CXU
GCHP | Aquamicron™ Check Solution P
SSX30M | Karl Fischer Reagent SSX-3mg
SSX10M | Karl Fischer Reagent SSX-1mg
OL2 | Aquamicron™ Solvent OL2
GEX | Aquamicron™ Solvent GEX
AWS100 | Aquamicron™ Water Standard 10mg H2O/g
AWS10 | Aquamicron™ Water Standard 1mg H2O/g
AWS02 | Aquamicron™ Water Standard 0.2mg H2O/g
AWS01 | Aquamicron™ Water Standard 0.1mg H2O/g
AKX | Aquamicron™ AKX
FLX | Aquamicron™ FLX
SWS | Aquamicron™ Solid Water Standard
SSZ10M (Manufactured before Feb, 2017) | Aquamicron™ Titrant SS-Z 1mg
SSZ10M (LOT No.B17066) | Aquamicron™ Titrant SS-Z 1mg
SSZ10M | Aquamicron™ Titrant SS-Z 1mg
SSZ30M | Aquamicron™ Titrant SS-Z 3mg
SSZ30L | Aquamicron™ Titrant SS-Z 3mg(L)
SSZ50M | Aquamicron™ Titrant SS-Z 5mg
SSZ50L | Aquamicron™ Titrant SS-Z 5mg(L)
OLX | Aquamicron™ Solvent OLX
KTX | Aquamicron™ Solvent KTX
FLS | Aquamicron™ FLS
分类：AQUAMICRON™
AQUAMICRON™,库仑法试剂,三菱化学,库仑法试剂 AKX CXU
Scope of Applications for Karl Fischer Method
How can be used with interference
| Compound | Interference reaction | Treatment | ||
|---|---|---|---|---|
| Volumetric titration | Coulometric titration | |||
| Ketones | React with methanol to produce ketal and water | Titrant SS-Z | Solvent KTX | AKX CXU |
| Titrant SS | Solvent CP | |||
| Aldehydes | React with methanol to produce acetal and water React with sulfur dioxide and water
与甲醇反应生成缩醛和水与二氧化硫反应生成水 |
Titrant SS-Z | Solvent KTX | AKX CXU (suitable only for a certain aromatic aldehydes) |
| Titrant SS | Solvent CP | |||
| Lower carboxylic acids | React with methanol to produce ester and water | Titrant SS-Z | Solvent KTX | AKX CXU |
| Titrant SS | Solvent CP | |||
| Amines above pKa 9 | Consume iodine gradually and the end-point becomes unstable | Titrant SS-Z | Solvent KTX | AKX CXU salicylic acid |
卡尔费歇尔法的适用范围,卡尔费歇尔法,三菱化学,AQUAMICRON™
卡尔·费希尔法可用于广泛的物质。然而，该方法依赖于一种基于卡尔·费舍尔试剂与水之间反应的碘量测定法。因此，如果样品中含有与碘反应的物质，则结果误差为正;如果样品中含有氧化碘化物产生碘的物质，则结果误差为负。下表列出了可以用卡尔·费歇尔试剂直接滴定的物质，不能直接滴定但可以根据适当的化学反应或过程通过调整滴定的物质，以及与卡尔·费歇尔试剂反应因而不适合直接滴定的物质。即使一种物质不能直接滴定，它的含水量也可以通过间接的方法测量，如水蒸汽法。
Compounds that can be titrated directly
| Organic compounds |
|---|
| Hydrocarbons(saturated, unsaturated compounds) Alcohols, Polyhydric alcohols, Phenols, Ethers Inert ketones(diisopropyl ketone, et al) Inert aldehydes(formaldehyde, chloral, et al) Organic acids, Hydroxylic acids, amino acids Acid anhydrides Esters, Lactones, Inorganic acid esters Amines(<pka9), amino=”” alcohols<br=””> Proteins, Amides, Anilides Nitriles, Cyanhydrins, Cyanic acid derivatives Nitro compounds, Oximes, Hydroxamic acids Thiocyanate, Thioethers, Thioesters Halogenated hydrocarbons, Halogenated acyls Sugars, Organic salts and their hydrates |
| Inorganic compounds |
| Inorganic salts and their hydrates Inorganic acids Chelate compounds Fertilizers Calcium carbonate Polytungsten salts |
Compounds that can be titrated directly after special processing or under certain conditions
经过特殊处理或在一定条件下可直接滴定的化合物
The examination will be necessary for the following compounds though it was said that these could be titrated directly by the following treatments in former references.
对下列化合物进行检查是必要的，尽管在以前的文献中说这些化合物可以通过下列处理直接滴定。
| Compound | Treatment |
|---|---|
| Ammonia | Add acetic acid. |
| Ferric salts | Add 8-hydroxyquinoline. |
| Hydrazine derivatives | Add acetic acid. |
| Hydroxylamine salts | Add sulfur dioxide: pyridine solution (1:1). |
| Thiol(mercaptan) | Prevent interference by adding olefins(octene, etc.). |
| Sulfuric acid | If the sulfuric acid is 92%pure or higher, add a large surplus of pyridine and titrate it as a salt. |
| Thioacid | Prevent interference by adding olefins(octene, etc.). |
| Thiourea | Prevent interference by adding olefins(octene, etc.). |
Compounds that react with Karl Fischer reagents and cannot be titrated directly
与卡尔·费舍尔试剂反应而不能直接滴定的化合物
| Organic compounds |
|---|
| Ascorbic acid, Diacyl peroxides Peracids, Quinone |
| Inorganic compounds |
| Sodium sulfide, Sodium peroxide Chromates, Dichromates Ferric oxide, Nickel oxide, Arsenic trioxide Arsenates, Arsenites, Borates, Boron oxide Hydrogencarbonates, Carbonates Metal hydroxides, Metal oxides Sulfites, Pyrosulfites Sodium nitrite, Thiosulfates Cupric salts, Stannous salts |
卡尔费舍试剂,库仑法试剂,AQUAMICRON™
卡尔费舍试剂含有碘、二氧化硫、甲醇、氯仿、碳酸丙烯等多种物质。概述
1.使用的有机溶剂必须按照当地法律等进行处理。
2.工作区域应配备局部或通用通风系统。
3.如有必要，在处理卡尔·费舍尔试剂时佩戴口罩和手套。小心避免溢出。
4.避免吸入试剂，避免皮肤接触。如果试剂接触到你的手，用肥皂清洗该区域，用大量的水冲洗。如果吸入烟雾后感到不适，应在空气干净的地方安静休息。如果试剂溅进眼睛，用清水清洗至少10分钟，然后咨询医生。
5.如果工作服被污染，请立即脱下被污染的衣服。
6.如果试剂溢出，在受影响的区域铺上沙子或类似的材料后处理掉。
7.在储存试剂时，要仔细密封瓶子，并选择阴凉和通风良好的储存地点。防止试剂被水污染。
8.在处理使用过的溶液时，应注意添加到试剂中的测量样品的特性，并使用不造成环境污染的处理方法。
Karl Fischer reagents contain iodine, sulfur dioxide, methanol, chloroform, propylene carbonate and various other substances. As outlined
- The organic solvents used must be handled in accordance with local laws, etc.
- Work areas should be equipped with localized or general ventilation systems.
- If necessary, wear a mask and gloves when handling Karl Fischer reagents. Take care to avoid spillage.
- Avoid inhaling reagents and avoid skin contact. If a reagent comes into contact with your hands, wash the area with soap and rinse with ample water. If you feel unwell after inhaling fumes, rest quietly in a location with clean air. If a reagent splashes into your eyes, wash them with clean water for least 10 minutes and then consult your physician.
- If work clothes are contaminated, remove the contaminated clothing immediately.
- If reagents are spilled, dispose of them after spreading sand or a similar material over the affected area.
- When storing reagents, seal the bottles carefully and select a storage location that is cool and well ventilated. Protect reagents from contamination by water.
- When disposing of used solutions, be aware of the characteristics of the measurement sample added to the reagent, and use a disposal method that does not result in environmental contamination.
标准水溶液,库仑法试剂,三菱化学
AQUAMICRON™ Water Standard …
- Manufactured at Mitsubishi Chemical Co. which have ISO9001 accreditation.
- According to ISO, GMP, GLP, and FDA guidelines. Traceable to NIST SRM2890.
- Consist of a solvent with specific composition, and exactly confirmed water content. Supplied with Certificate of Analysis.
- Packaged in single-use glass ampoules.
- Long shelf life.
| Product name | Use | Specification | Package | |
|
For Coulometric Titration
|
AQUAMICRON™ Water Standard 0.1 |
For checking the accuracy of the coulometric moisture meter | Titer 0.1±0.01mgH2O/g |
5mL x10/case |
| AQUAMICRON™ Water Standard 0.2 |
For checking the accuracy of the coulometric moisture meter | Titer 0.2±0.01mgH2O/g |
5mL x10/case |
|
| AQUAMICRON™ Water Standard 1 |
For checking the accuracy of the coulometric moisture meter | Titer 1±0.05mgH2O/g |
5mL x10/case |
|
| AQUAMICRON™ Check Solution P |
The end-point adjustment solution can be used with both AX and AKX. It can also be used for day-to-day management of coulometric moisture mesurement systems. | Moisture 3.8-4.2mgH2O/g |
100mL | |
|
For Volumetric Titration
|
AQUAMICRON™ Water Standard 10 |
For determination of Karl Fischer reagent titer | Titer 10±0.5mgH2O/g |
8mL x10/case |
| AQUAMICRON™ Standard Water/Methanol |
Used to assess titer of Karl Fischer reatents(3-10mgH2O/mL). Also can be used for reverse titration. | Moisture 2.0±0.04mgH2O/g |
250mL | |
|
For Vaporization Method
|
AQUAMICRON™ Solid Water Standard |
For evaluation a moisture meter with a water vaporizer | Moisture 3.83±0.1% |
10g |
Volumetric Reagents,三菱化学,三菱化学代理
体积滴定所需要的物品是卡尔·费歇尔滴定剂和甲醇或脱水溶剂(用于溶解或分散样品)。
AQUAMICRON™提供了广泛的产品，适用于测量不同水平的各种样品的水分含量。用户可根据下表选择适合样品的溶剂。
AQUAMICRON™提供了广泛的产品，适用于测量不同水平的各种样品的水分含量。用户可根据下表选择适合样品的溶剂。
SS Series (pyridine type)
| Product name | Use | Specification | Package | |
|
AQUAMICRON™
|
Titrant SS 1mg | [For General-use] Low moisture content Samples |
Titer 0.7〜1.2 mgH2O/mL |
500mL |
| Titrant SS 3mg | [For General-use] | Titer 2.5〜3.5 mgH2O/mL |
500mL | |
| Titrant SS 10mg | [For General-use] High moisture content Samples |
Titer 8〜12 mgH2O/mL |
500mL | |
| Solvent ML | [For General-use] Organic solvents, Inorganic chemicals, Agricultural chemicals, Pharmaceuticals, Fertilizers, Detergents, Foodstuffs, etc. |
Moisture maximum 0.2 mgH2O/mL |
500mL | |
| Solvent MS | [For General-use] Organic solvents, Inorganic chemicals, Agricultural chemicals, Pharmaceuticals, Fertilizers, Detergents, Foodstuffs, etc. |
Moisture maximum 0.2 mgH2O/mL |
500mL | |
| Solvent CM | [For Oils] Naphtha, Gasolone, Diesel oil, Heavy oil, Electrical insulation oil, Oils and Fats(Hardened oil, Margarine, etc.),etc. |
Moisture maximum 0.3 mgH2O/mL |
500mL | |
| Solvent CP | [For Ketones] Ketones, Silicone oils, Acetic and other lower carboxylic acids, aldehydes(except acetaldehydes),Anilines, etc. |
Moisture maximum 0.5 mgH2O/mL |
500mL | |
| Solvent PP | [For Aldehydes] Acetaldehydes, propionaldehydes, Butyraldehydes, etc. |
Moisture maximum 0.2 mgH2O/mL |
500mL | |
| Solvent PE | [For Ketones] Ketones, Silicone oils, Acetic and other lower carboxylic acids, aldehydes(except acetaldehydes),Anilines, etc. |
Moisture maximum 0.2 mgH2O/mL |
500mL | |
| Solvent FM | [For Sugars] Sugars, Proteins, Gelatine, Additives, Animal feeds, etc. |
Moisture maximum 0.2 mgH2O/mL |
500mL | |
| Solvent ME | [For Vaporizer] Gaseous samples, Nitrogen, etc. | Moisture maximum 0.2 mgH2O/mL |
500mL | |
- When using a moisture vaporization method, mix Solvent MS with propylene glycol(PG) in a 3:1 ratio (e.g. 90mL of MS + 30mL of PG).
- An addition of 3g of salicylic acid enables the time for dehydration to get shorter at the first measurement in combined use of 50mL of Solvent FM.
- 当使用水汽汽化方法时，将溶剂MS与丙二醇(PG)按3:1的比例混合(例如90mL MS + 30mL PG)。
加入3g水杨酸使脱水时间在第一次测量时缩短，同时使用50mL的溶剂FM。
Volumetric Reagents,体积试剂,三菱化学
The items required for volumetric titration are a Karl Fischer titrant and methanol or a dehydrated solvent (used to dissolve or disperse the sample).
AQUAMICRON™ offers a wide range of products suitable for measuring the moisture content of various samples at every levels. Users can select a solvent that is suitable for the samples based on the following tables.
SS-Z Series (pyridine-free and chloroform-free type)
| Product name | Use | Specification | Package | |
|
AQUAMICRON™
|
Titrant SS-Z 1mg | [For General-use] Low moisture content Samples |
Titer 0.7〜1.2 mgH2O/mL |
500mL |
| Titrant SS-Z 3mg | [For General-use] | Titer 2.5〜3.5 mgH2O/mL |
500mL | |
| 1L | ||||
| Titrant SS-Z 5mg | [For General-use] High moisture content Samples |
Titer 4.5〜5.5 mgH2O/mL |
500mL | |
| 1L | ||||
| Solvent GEX | [For General-use] Organic solvents, Inorganic chemicals, Agricultural chemicals, Pharmaceuticals, Fertilizers, Detergents, Foodstuffs, etc. |
Moisture maximum 0.2 mgH2O/mL |
500mL | |
| Solvent OLX | [For Oils] Naphtha, Gasolone, Diesel oil, Electrical insulation oil, etc. |
Moisture maximum 0.5 mgH2O/mL |
500mL | |
| Solvent OLII | [For Oils and Fats] Naphtha, Gasolone, Diesel oil, Heavy oil, Electrical insulation oil, Oils and Fats(Hardened oil, Margarine, etc.),etc. |
Moisture maximum 0.2 mgH2O/mL |
500mL | |
| Solvent KTX | [For Ketones] Ketones, Silicone oils, Acetic and other lower carboxylic acids, aldehydes(except acetaldehydes),etc. |
Moisture maximum 0.5 mgH2O/mL |
500mL | |
| Solvent SU | [For Sugars] Sugars, Proteins, Gelatine, Additives, Animal feeds, etc. |
Moisture maximum 0.2 mgH2O/mL |
500mL | |
- When using a moisture vaporization method, mix Solvent GEX with propylene glycol(PG) in a 3:1 ratio (e.g. 90mL of GEX + 30mL of PG).
- When using Solvent KTX, it will be needed to make proper adjustments to the parameters. Please contact a manufacturer of the instruments.
- An addition of 3g of salicylic acid enables the time for dehydration to get shorter at the first measurment in combined use of 50mL of Solvent SU.
- 当使用水分汽化方法时，将溶剂GEX与丙二醇(PG)按3:1的比例混合(例如:90mL GEX + 30mL PG)。
在使用溶剂KTX时，需要对参数进行适当的调整。请与仪器的制造商联系。
加入3g的水杨酸使脱水时间在第一次测量时缩短，同时使用50mL的溶剂SU。
AQUAMICRON™ FLS,库仑法试剂,三菱化学
| Use | Suitable for alcohols, esters, benzene, toluene, inorganic gases, etc. | |
|---|---|---|
| Characteristics | Easy to use | AQUAMICRON™ AXI or FLS is a single-solution type reagent. It should be used in single-solution electrolytic cells without diaphragm, fritless type cell. Can be used with moisture vaporizati on method(When using AQUAMICRON™ AXI or FLS in a moisture vaporization method, replenish the vaporized portion with methanol.) AQUAMICRON™AXI或FLS是单溶液型试剂。适用于无隔膜的单溶液电解槽、无气泡电解槽。 |
| Easy to use | Ceramic diaphragm is not used, therefore it is easy to maintain electrolytic cell in good condition.
不使用陶瓷隔膜，容易使电解槽保持良好状态。 |
|
AQUAMICRON™ AKX/CXU,库仑法试剂,三菱化学
| Use | Ketones, lower carboxylic acids, some aldehydes (aromatics) | |
|---|---|---|
| Characteristics | Minimal environmental contamination | Does not include chloroform or methyl cellosolve |
| Wide range of applications | Suitable for ketones, lower carboxylic acids and some aldehydes | |
| High quality, high performance | Accurate moisture measurement, good end-point stability Approximately 300mg of moisture can be measured per 100ml of AQUAMICRON™ AKX, and approximately 100mg per 5mL of AQUAMICRON™ CXU (when used with AQUAMICRON™ AKX). 水分测量准确，终点稳定性好 |
|
| Easy to use | These products can be used in the existing coulometric moisture measurement system.
这些产品可用于现有的库仑湿度测量系统。 |
|
三菱化学,库仑法试剂,AQUAMICRON™ AS/CXU
| Use | General samples | |
|---|---|---|
| Characteristics | Wide range of applications | Especially suitable for oils, petroleum products
特别适用于油品、石油制品 |
| High quality, high performance | Excellent reputation for accurate moisture measurement and end-point stability. Approximately 800mg of moisture can be measured per 100mL of AQUAMICRON™ AS, and approximately 150mg per 5mL of AQUAMICRON™ CXU. 准确的水分测量和端点稳定性的良好声誉。 |
|
| Easy to use | These products can be used in the existing coulometric moisture measurement system.
这些产品可用于现有的库仑湿度测量系统。 |
|
库仑法试剂,三菱化学,AQUAMICRON™ AXI/CXU or AX/CXU
| Use | General samples | |
|---|---|---|
| Characteristics | Minimal environmental contamination | Does not include carbon tetrachloride or chloroform. |
| Wide range of applications | Suitable for petroleum products Can be used with moisture vaporization method (When using AQUAMICRON™ AX or AXI in a moisture vaporization method, replenish the vaporized portion with methanol.) 适用于石油产品 |
|
| High quality, high performance | Excellent reputation for accurate moisture measurement and end-point stability Approximately 800mg of moisture can be measured per 100mL of AQUAMICRON™ AX or AXI, and approximately 150mg per 5mL of AQUAMICRON™ CXU 准确的水分测量和端点稳定性的良好声誉 |
|
| Easy to use | These products can be used in the existing coulometric moisture measurement system.
这些产品可用于现有的库仑湿度测量系统。 |
|
库仑法试剂,三菱化学,AQUAMICRON™ Series
AQUAMICRON™ Series
There are two types of coulometric reagents: the anolyte (generating solution),which is placed in the anode chamber of the electrolysis cell, and the catholyte (counter electrolyte), which is placed in the cathode chamber. There are also special anolyte for use with ketones, lower carboxylic acids and silicone oils. AQUAMICRON™ can be used in coulometric moisture measurement systems sold by various companies, and it has a worldwide reputation for excellent performance.
库仑试剂有两种类型:阳极液(生成溶液)，放置在电解池的阳极室，和阴极液(反电解质)，放置在阴极室。也有特殊的阳极液用于酮，低羧酸和硅油。AQUAMICRON™可用于各种公司销售的库仑湿度测量系统，并以优异的性能享誉全球。
| Product name | Use | Specification | Package | |
|---|---|---|---|---|
|
AQUAMICRON™
|
AXI | *AXI [For frit or fritless type cell, equivalent to FLS] *AXI, AX & AX01[For General-use] Organic solvents, Inorganic chemicals, Oiles, Petroleum products, Various kind of gases, etc. |
Moisture maximum 0.15 mgH2O/mL |
500mL |
| AX | ||||
| AX01 | 100mL | |||
| AS | [For Oils] Naphtha, Gasolone, Diesel oil, Electrical insulation oil, etc. |
Moisture maximum 0.15 mgH2O/mL |
500mL | |
| AKX | [For Ketones] Ketones. Silicone oils. Low carboxylic acids, etc. |
Moisture maximum 0.15 mgH2O/mL |
500mL | |
| CXU | [Catholyte] Both AX and AS and AKX available to combine with |
Moisture maximum 0.6 mgH2O/mL |
5mL x10/case |
|
| FLS | [For fritless type cell] Organic solvents, Inorganic gases, etc. |
Moisture maximum 0.15 mgH2O/mL |
500mL | |
三菱化学代理,库仑法试剂,AQUAMICRON™,AQUAMICRON™ Series
Coulometric Reagents,库仑法试剂
- AQUAMICRON™ AXI
- AQUAMICRON™ AX
- AQUAMICRON™ AX01
- AQUAMICRON™ AS
- AQUAMICRON™ AKX
- AQUAMICRON™ CXU
- AQUAMICRON™ FLS
Volumetric Reagents
- AQUAMICRON™ Titrant SS-Z 1mg
- AQUAMICRON™ Titrant SS-Z 3mg
- AQUAMICRON™ Titrant SS-Z 5mg
- AQUAMICRON™ Solvent GEX
- AQUAMICRON™ Solvent OLX
- AQUAMICRON™ Solvent OLII
- AQUAMICRON™ Solvent KTX
- AQUAMICRON™ Solvent SU
- AQUAMICRON™ Titrant SS 1mg
- AQUAMICRON™ Titrant SS 3mg
- AQUAMICRON™ Titrant SS 10mg
- AQUAMICRON™ Solvent ML
- AQUAMICRON™ Solvent MS
- AQUAMICRON™ Solvent CM
- AQUAMICRON™ Solvent CP
- AQUAMICRON™ Solvent PP
- AQUAMICRON™ Solvent PE
- AQUAMICRON™ Solvent FM
- AQUAMICRON™ Solvent ME
Water Standard
- For Coulometric Titration
- AQUAMICRON™ Water Standard 0.1
- AQUAMICRON™ Water Standard 0.2
- AQUAMICRON™ Water Standard 1
- AQUAMICRON™ Check Solution P
- For Volumetric Titration
- AQUAMICRON™ Water Standard 10
- AQUAMICRON™ Standard Water/Methanol
- For Vaporization Method
- AQUAMICRON™
- Solid Water Standard